It has been found that for a chemical reaction with rise in temperature by 9   K the rate constant gets…

It has been found that for a chemical reaction with rise in temperature by 9 K the rate constant gets doubled. Assuming a reaction to be occurring at 300 K, the value of activation energy is found to be kJmol-1. [nearest integer] (Given ln10=2.3,R=8.3 J K-1 mol-1,log2=0.30)

Solution

 Arrhenius equation for the rate constant of a reaction in terms of energy of activation at two different temperatures is given by

logK2K1=Ea2.3R1T1-1T2

Rise in temperature =9 K

Initial temperature =300 K

logK309K300=Ea2.3R1300-1309

log2=Ea2.3R9300×309

Ea=2.3×0.30×300×3099

Ea=58.988×103 J=58.988kJ=59kJ

Asked in: JEE Main 2022 (27 Jun Shift 2)

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