$\mathrm{CN}^{-}$is strong field ligand. This is due to the fact that :

$\mathrm{CN}^{-}$is strong field ligand. This is due to the fact that :
  1. it carries negative charge
  2. it is a pseudohalide
  3. it can accept electrons from metal species
  4. it form high spin complexes with metal species

Solution

Cyanide ion is strong field ligand because it is a pseudohalide ion. Pseudohalide ions are stronger coordinating ligand & they have the ability to form $\sigma$ bond (from the pseudohalide to the metal) and $\pi$ bond (from the metal to pseudohalide). Related Theory A pseudohalide is an anion which has similar properties to a halogen, but not a real halogen. Pseudohalogens are polyatomic analogues of halogens, or also called 'fake' halogens, whose properties resemble that of true halogens.

Asked in: NEET 2004

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