Ionisation potential of hydrogen atom is $13.6 \mathrm{eV}$. When hydrogen atoms in ground state are excited…

Ionisation potential of hydrogen atom is $13.6 \mathrm{eV}$. When hydrogen atoms in ground state are excited by a supply of $12.1 \mathrm{eV}$, then the number of spectral lines emitted by hydrogen atoms according to Bohr's theory is
  1. $2$
  2. $3$
  3. $1$
  4. $4$

Solution

Given that, ionisation potential of hydrogen atom, $E_1=-13.6 \mathrm{eV}$ Energy supplied = Energy absorbed by hydrogen atom. $\Delta E=12.1 \mathrm{eV}$ i.e. final energy of excited state, $E_2=\frac{-13.6 \mathrm{eV}}{n^2}$ We know that, $E_2-E_1=\Delta E$ $\Rightarrow \quad E_2=\Delta E+E_1$ Substituting the value, we get $\begin{aligned} & -\frac{13.6}{n^2}=[12.1+(-13.6)] \\ & -\frac{13.6}{n^2}=-1.50 \Rightarrow x^2=9.07 \Rightarrow n \simeq 3\end{aligned}$ Hence, by absorbing $12.1 \mathrm{eV}$ energy electron jump into 2nd excited state $(n=3)$. Then, number of spectral lines emitted by $\mathrm{H}$-atom $=\frac{n(n-1)}{2}=\frac{3(3-1)}{2}=3$

Asked in: AP EAMCET 2021 (23 Aug Shift 2)

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