Indicate the complex/complex ion which did not show any geometrical isomerism :

Indicate the complex/complex ion which did not show any geometrical isomerism :
  1. CoNH34Cl2+
  2. CoNH33NO23
  3. Co(CN)5(NC)3-
  4. CoCl2(en)2

Solution

1CoNH34Cl2+show cis-trans isomerism.
2CoCl2(en)2 show cis-trans isomerism.
3CoNH33NO23 show fac-mer isomerism.
4[Co(CN)5(NC)]3-can't show geometrical isomerism due to the presence of plane of symmetry.

Asked in: JEE Main 2021 (26 Aug Shift 2)

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