In which of the following reactions, the product is not correct?

In which of the following reactions, the product is not correct?
  1. $\mathrm{CH}_3 \mathrm{CHO} \stackrel{\mathrm{LiAlH}_4}{\longrightarrow} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}$


  2. $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CHO} \stackrel{\mathrm{KMnO}_4}{\longrightarrow} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{COOH}$

Solution

Clemmensen reduction:

Asked in: AP EAMCET 2016

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