In which of the following reactions, hydrogen is liberated? (i) $\mathrm{Al}(s)+\mathrm{HCl}(a q)…

In which of the following reactions, hydrogen is liberated? (i) $\mathrm{Al}(s)+\mathrm{HCl}(a q) \longrightarrow$ (ii) $\mathrm{Al}(s)+\mathrm{NaOH}(a q) \longrightarrow$ (iii) $\mathrm{NaBH}_4+\mathrm{I}_2 \longrightarrow$
  1. i, ii
  2. ii, iii
  3. i, iii
  4. i, ii, iii

Solution

(i) $2 \mathrm{Al}(s)+6 \mathrm{HCl}(a q) \longrightarrow 2 \mathrm{AlCl}_3(a q)+3 \mathrm{H}_2$ (ii) $ \begin{aligned} 2 \mathrm{Al}(s)+2 \mathrm{NaOH}(a q) \longrightarrow & \\ & 2 \mathrm{Na}\left[\mathrm{Al}(\mathrm{OH})_4\right]+3 \mathrm{H}_2 \\ & \begin{array}{l} \text { Sodium tetrahydroxo } \\ \text { aluminate (III) } \end{array} \end{aligned} $ (iii) $ \begin{aligned} \mathrm{NaBH}_4+\mathrm{I}_2 \longrightarrow & \mathrm{BH}_3+\mathrm{NaI}+\mathrm{HI} \\ & \downarrow\left(\mathrm{NaBH}_4\right) \\ & 2 \mathrm{BH}_3+2 \mathrm{NaI}+\mathrm{H}_2 \end{aligned} $

Asked in: AP EAMCET 2017 (26 Apr Shift 1)

Practice more p Block Elements (Group 13 & 14) questions on Aicharya