In the sulphur estimation, 0.20 g of a pure organic compound gave 0.40 g of barium sulphate. The percentage…

In the sulphur estimation, 0.20 g of a pure organic compound gave 0.40 g of barium sulphate. The percentage of sulphur in the compound is ______ $\times 10^{-1} \%$.
(Molar mass : $\mathrm{O}=16, \mathrm{~S}=32, \mathrm{Ba}=137$ in $\mathrm{g} \mathrm{mol}^{-1}$)

Solution

$\begin{array}{ll}\text { Organic Compound } \longrightarrow & \mathrm{BaSO}_4 \\ 0.20 \mathrm{gm} & 0.40 \mathrm{gm} \\ & \frac{0.40}{233} \mathrm{~mol}\left(\mathrm{BaSO}_4\right) \\ & \frac{0.40}{233} \mathrm{~mol} \text { (Sulphur) } \\ & \frac{0.40}{233} \times 32 \mathrm{gm} \text { (sulphur) }\end{array}$
$\% \mathrm{~S}=\frac{\frac{0.40 \times 32}{233} \times 100}{0.20}=27.5 \%$ or $275 \times 10^{-1} \%$

Asked in: JEE Main 2025 (29 Jan Shift 2)

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