In the reaction $3 \mathrm{Br}_{2}+6 \mathrm{CO}_{3}^{2-}+3 \mathrm{H}_{2} \mathrm{O} \rightarrow 5…

In the reaction $3 \mathrm{Br}_{2}+6 \mathrm{CO}_{3}^{2-}+3 \mathrm{H}_{2} \mathrm{O} \rightarrow 5 \mathrm{Br}^{-}+\mathrm{BrO}_{3}^{-}+6 \mathrm{HCO}_{3}^{-}$
  1. Bromine is oxidised and carbonate is reduced.
  2. Bromine is reduced and water is oxidised.
  3. Bromine is neither reduced nor oxidised.
  4. Bromine is both reduced and oxidised.

Solution

$\begin{aligned} 3 \mathrm{Br}_{2}+6 \mathrm{CO}_{3}^{2-}+3 \mathrm{H}_{2} \mathrm{O} & \rightarrow \\ 5 \mathrm{Br}^{-} &+\mathrm{BrO}_{3}^{-}+6 \mathrm{HCO}_{3}^{-} \end{aligned}$ O.N. of $\mathrm{Br}_{2}$ changes from 0 to -1 and +5 , hence it is reduced as well as oxidised.

Asked in: BITSAT 2012

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