In the ground state of hydrogen atom. electron absorbs 1.5 times energy than the minimum energy $\left(2.18…

In the ground state of hydrogen atom. electron absorbs 1.5 times energy than the minimum energy $\left(2.18 \times 10^{-18} \mathrm{~J}\right)$ to escape from the atom. The wavelength of the emitted electron (in m) is $\left(m_e=9 \times 10^{-31} \mathrm{~kg}\right)$
  1. $\frac{h \times 10^{24}}{\sqrt{1.962}}$
  2. $\frac{h}{\sqrt{1.962}} \times 10^{23}$
  3. $\frac{h}{\sqrt{1.962}} \times 10^{25}$
  4. $\frac{h}{\sqrt{1.962}} \times 10^{22}$

Solution

Energy absorbed by the element $\begin{aligned} & =1.5 \times 2.18 \times 10^{-18} \mathrm{~J} \\ & =1.5 \times 2.18 \times 10^{-18} \mathrm{kgm}^2 \mathrm{~s} \mathrm{~s}^{-2} \\ & =3.27 \times 10^{-18} \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-2} \end{aligned}$ Energy required $=2.18 \times 10^{-18} \mathrm{~J}$ Kinetic energy of the emitted electron $\begin{aligned} & =\text { Energy absorbed }- \text { energy required } \\ & =\left(3.27 \times 10^{-18}-2.18 \times 10^{-18}\right) \mathrm{kg} \mathrm{~m}^2 \mathrm{~s}^{-2} \\ & \mathrm{KE}=1.09 \times 10^{-18} \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-2} \\ & \quad \mathrm{~m}_{\mathrm{e}}=9 \times 10^{-31} \mathrm{~kg} \end{aligned}$ According to de Broglie equation $\lambda=\frac{\mathrm{h}}{\mathrm{~m} v} \mathrm{KE}=\frac{1}{2} \mathrm{~m} v^2$ $\begin{aligned} & v=\left(\frac{2 \times \mathrm{KE}}{\mathrm{~m}}\right)^{1 / 2} \\ & \therefore \lambda=\frac{\mathrm{h}}{\sqrt{2 \mathrm{mK} \cdot \mathrm{E}}} \end{aligned}$ or, $\lambda=\frac{\mathrm{h}}{\sqrt{2 \times 9 \times 10^{-31} \mathrm{~kg} \times 1.09 \times 10^{-18} \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-2}}}$ or, $\lambda=\frac{h}{\sqrt{19.62 \times 10^{-49}}}$ $\lambda=\frac{\mathrm{h}}{\sqrt{1.962 \times 10^{-48}}} \Rightarrow \lambda=\frac{\mathrm{h} \times 10^{24}}{\sqrt{1.962}}$

Asked in: AP EAMCET 2024 (19 May Shift 2)

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