In the context of the Hall-Heroult process for the extraction of Al, which of the following statements is…

In the context of the Hall-Heroult process for the extraction of Al, which of the following statements is false ?
  1. CO and C O 2 are produced in this process
  2. A l 2 O 3 is mixed with C a F 2 which lowers the melting point of the mixture and brings conductivity
  3. A l 3 + is reduced at the cathode to form Al
  4. N a 3 A l F 6 helps in increasing the melting point of the mixture

Solution

Hall heroult process:

In the Hall-Héroult process the following simplified reactions take place at the carbon electrodes:

Cathode: A l 3 + + 3 e - 1 A l

Anode: O 2 - + C C O + 2 e -  


Overall:
A l 2 O 3 + 3 C 2 A l + 3 C O

And 2   A l 2 O 3 + 3 C 4 A l + 3 C O 2


In reality, much more C O 2 is formed at the anode than C O :

Cryolite ( N a 3 A l F 6 ) lowers the melting point of the mixture and make it more conductive in nature so as to carry out electrolysis of the ore in Hall-Heroult process. ^

Asked in: JEE-TOPICTESTS-CHEMISTRY

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