In Lassaigne's extract of organic compound both nitrogen and sulphur are present, which gives blood-red…

In Lassaigne's extract of organic compound both nitrogen and sulphur are present, which gives blood-red colour with Fe3+ due to the formation of
  1. FeSCN2+
  2. Fe4FeCN63.xH2O
  3. NaSCN
  4. FeCN5NOS4-

Solution

When the organic sample containing nitrogen and sulphur is strongly heated with sodium metal the ionic compound sodium thiocyanate is formed. Sodium thiocyanate gives blood-red colour with neutral FeCl3.

Na +N+C+SNaSCNSCN-  + Fe3+FeSCN2+

Asked in: NEET 2023 (All India)

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