In Carius tube, an organic compound ' X ' is treated with sodium peroxide to form a mineral acid…

In Carius tube, an organic compound ' X ' is treated with sodium peroxide to form a mineral acid ' Y '. The solution of BaCl2 is added to ' Y ' to form a precipitate ' Z '. ' Z ' is used for the quantitative estimation of an extra element. ' X ' could be
  1. Cytosine
  2. A nucleotide
  3. Methionine 
  4. Chloroxylenol

Solution

Barium chloride is used estimate sulphur content in the molecule. In Carius tube test, a known mass of sulphur present in an organic compound with Silver Nitrate is heated into a sealed tube known as Carius tube with silver. The organic compound is then converted to Sulphuric acid which then reacts with excess Barium Chloride solution and produces a precipitate of Barium Sulphate. Z is BaSO4 and Y is H2SO4

It is clear that " X " must contain sulphur. Methionine is C5H11NO2 S, a sulphur contaning amino acid

Asked in: JEE Main 2023 (10 Apr Shift 2)

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