In Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl. The…

In Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl. The percentage composition of chlorine in the compound is _______ %.
(Given : molar mass in $\mathrm{g} \mathrm{mol}^{-1}$ of $\mathrm{Ag}: 108, \mathrm{Cl}: 35.5$)

Solution

$\begin{aligned} & \mathrm{n}_{\mathrm{Cl}}=\mathrm{n}_{\mathrm{AgCl}}=\frac{143.5 \times 10^{-3}}{143.5}=10^{-3} \\ & \% \mathrm{Cl}=\frac{10^{-3} \times 35.5}{180 \times 10^{-3}} \times 100=19.72\end{aligned}$

Asked in: JEE Main 2025 (22 Jan Shift 1)

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