In Balmer series, wavelength of the $2^{\text {nd }}$ line is ' $\lambda_1$ ' and for Paschen series,…

In Balmer series, wavelength of the $2^{\text {nd }}$ line is ' $\lambda_1$ ' and for Paschen series, wavelength of the $1^{\text {st }}$ line is ' $\lambda_2$ ', then the ratio ' $\lambda_1$ ' to ' $\lambda_2$ ' is
  1. $5: 128$
  2. $5: 81$
  3. $7: 27$
  4. $9: 132$

Solution

For spectral series, $\frac{1}{\lambda}=R Z^2\left(\frac{1}{\mathrm{n}_1^2}-\frac{1}{\mathrm{n}_2^2}\right)$ For the Balmer series, $\mathrm{n}_1=2$ The wavelength for $2^{\text {nd }}$ line of the Balmer series is $\begin{aligned} & \frac{1}{\lambda_1}=\mathrm{RZ}^2\left(\frac{1}{2^2}-\frac{1}{4^2}\right) \\ & \frac{1}{\lambda_1}=\mathrm{RZ}^2\left(\frac{1}{4}-\frac{1}{16}\right) \\ & \frac{1}{\lambda_1}=\mathrm{RZ}^2\left(\frac{3}{16}\right) \Rightarrow \lambda_1=\left[\frac{16}{3}\right] \end{aligned}$ For the Paschen series, $\mathrm{n}_1=3$ The wavelength for $1^{\text {st }}$ line of the Paschen series is $\begin{aligned} \frac{1}{\lambda_2} & =\mathrm{RZ}^2\left(\frac{1}{3^2}-\frac{1}{4^2}\right) \\ \frac{1}{\lambda_2} & =\mathrm{RZ}^2\left(\frac{1}{9}-\frac{1}{16}\right) \\ \lambda_2 & =\frac{144}{7} \\ \frac{1}{\lambda_2} & =\mathrm{RZ}^2\left(\frac{7}{144}\right) \\ \therefore \quad \frac{\lambda_1}{\lambda_2} & =\frac{16}{3} \times \frac{7}{144}=\frac{7}{27} \end{aligned}$

Asked in: MHT CET 2023 (12 May Shift 2)

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