In a buffer solution having equal concentrations of B - and HB the value of K b for B - is 1 0 - 9 . The pH…

In a buffer solution having equal concentrations of B - and HB the value of K b for B - is 1 0 - 9 . The pH of buffer solution is
  1. 9
  2. 5
  3. 4
  4. 6

Solution

For acidic buffer pH can be find out as follows
pH = pKa + lo g 10 [ s a l t ] [ a c i d ]

As here K b = 1 0 - 9

So K a = 1 0 - 5
p K a = 5

As pH = 5 + l o g 10 [ B - ] [ H B ]

As [ B - ] = [ HB ]
pH = 5 + log 1 = 5 + 0 = 5

Asked in: JEE-TOPICTESTS-CHEMISTRY

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