If two liquids A and B form a minimum boiling azeotrope at some specific composition, then which statement…

Minimum Boiling Azeotropes :-

Non-ideal solutions showing large positive deviation from Raoult's law form minimum boiling azeotropes which boil at temperature lower than boiling point of its components $\text{'}\mathrm{A}\text{'}$ and $\text{'}\mathrm{B}\text{'}$, e.g., water and benzene, chloroform and methanol.

The Minimum Boiling Azeotropes has the $\mathrm{A}-\mathrm{B}$ molecular interactions are weaker than $\mathrm{A}-\mathrm{A}$ and $\mathrm{B}-\mathrm{B}$ interactions. They has the total vapour pressure of the mixture is greater than that corresponding to an ideal solution. There is a slight increase in volume when the two components are mixed.  ${\mathrm{\Delta H}}_{mix}$ will have positive value.

Hence, the correct statement is that the total vapour pressure of the mixture is greater than that corresponding to an ideal solution.