If the rate constant of a first order reaction is $4.606 \times 10^{-3} \mathrm{~s}^{-1}$, then find the…

If the rate constant of a first order reaction is $4.606 \times 10^{-3} \mathrm{~s}^{-1}$, then find the time required for $400 \mathrm{~g}$ of the reactant to reduce to $50 \mathrm{~g}$.
  1. 7.52 min
  2. 0.45 min
  3. 46.06 min
  4. 15.05 min

Solution

Given, Rate constant, $k=4.606 \times 10^{-3} \mathrm{~s}^{-1}$ Concentration at, time $t=50 \mathrm{~g}$ Initial concentration $=400 \mathrm{~g}$ Now, formula, $ \begin{aligned} k & =\frac{2.303}{t} \log \frac{A_0}{A_t} \\ t & =\frac{2.303}{4.606 \times 10^{-3}} \log \frac{400}{50} \\ & =\frac{2.303}{0.00460} \log 8 \\ & =\frac{2.303 \times 0.9030}{0.00460} \\ & =452.08 \mathrm{~s}=\frac{452.08}{60} \mathrm{~min} \\ t & =7.52 \mathrm{~min} \end{aligned} $

Asked in: AP EAMCET 2021 (25 Aug Shift 2)

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