If the magnetic moment of a di-oxygen species is 1.73  B . M . , it may be

If the magnetic moment of a di-oxygen species is 1.73 B.M., it may be
  1. O2- or O2+.
  2. O2 or O2+.
  3. O2 or O2-.
  4. O2,O2- or O2+.

Solution

Given, magnetic moment of di-oxygen species=1.73 B.M.

We know, magnetic moment = n n+2 , where n=number of unpaired electrons

1.73= n n+2

n=1
So, species should contain one unpaired electron.

Let us check by electronic configuration of each species

O2=σ1s2 σ*1s2 σ2s2 σ*2s2 σ2p2z π2p2x=π2p2y π*2p1x=π*2p1yO2+=σ1s2 σ*1s2 σ2s2 σ*2s2 σ2p2z π2p2x=π2p2y π*2p1x=π*2p0yO2-=σ1s2 σ*1s2 σ2s2 σ*2s2 σ2p2z π2p2x=π2p2y π*2p2x=π*2p1y
 

As clear by above electronic configurations that, O2 has two unpaired electrons and O2- & O2+  Each has only one unpaired electron; hence magnetic moment of  O2+ & O2- is 1.73 B.M.

Asked in: JEE Main 2020 (09 Jan Shift 1)

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