If the bond length and dipole moment of a diatomic molecule are $1.25 \mathrm{~A}$ and $1.0 \mathrm{D}$…

If the bond length and dipole moment of a diatomic molecule are $1.25 \mathrm{~A}$ and $1.0 \mathrm{D}$ respectively, what is the per cent ionic character of the bond?
  1. 10.66
  2. 12.33
  3. 16.66
  4. 19.33

Solution

$\mu$ experimental $=$ Dipole moment $\times 10^{-18}$ $\mu$ theoretical $=$ Bond length $\times 4.8 \times 10^{-10} \times 10^{-8} \mathrm{esu} \times \mathrm{cm}$ Per cent ionic character $=\frac{\mu_{\text {experimental }}}{\mu_{\text {theoretical }}} \times 100$ $=\frac{1.0 \times 10^{-18} \times 100}{1.25 \times 4.8 \times 10^{-10} \times 10^{-8}}=16.66 \%$ ~

Asked in: JEE-TOPICTESTS-CHEMISTRY

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