If ' $\Delta Q^{\prime}$ is the amount of heat supplied to 'n' moles of a diatomic gas at constant pressure,…

If ' $\Delta Q^{\prime}$ is the amount of heat supplied to 'n' moles of a diatomic gas at constant pressure, ' $\triangle \mathrm{U}^{\prime}$ is the change in internal energy and ' $\triangle \mathrm{W}^{\prime}$ is the work done, then $\Delta \mathrm{W}: \Delta \mathrm{U}: \Delta \mathrm{Q}$ is
  1. $2: 3: 4$
  2. $1: 2: 3$
  3. $2: 5: 7$
  4. $5: 7: 9$

Solution

We know, $\begin{array}{l} \Delta \mathrm{Q}=\mathrm{nC}_{\mathrm{p}} \Delta \mathrm{T} \\ \Delta \mathrm{U}=\mathrm{nC}_{\mathrm{v}} \Delta \mathrm{T} \\ \mathrm{W}=\mathrm{P} \Delta \mathrm{V}=\mathrm{nR} \Delta \mathrm{T} \\ \Delta \mathrm{W}: \Delta \mathrm{U}: \Delta \mathrm{Q}=\mathrm{R}: \mathrm{C}_{\mathrm{v}}: \mathrm{C}_{\mathrm{p}} \end{array}$ For a diatomic gas $f=5$ $\begin{aligned} \therefore \quad & C_{v}=\frac{f}{2} R=\frac{5}{2} R \\ & C_{p}=C_{v}+R=\frac{7}{2} R \\ \therefore \quad R: C_{v}: C_{p}=1: \frac{5}{2}: \frac{7}{2}=2: 5: 7 \end{aligned}$

Asked in: MHT CET 2020 (15 Oct Shift 1)

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