If $^{\prime} \lambda_{1}$ ' and ' $\lambda_{2}$ ' are the wavelengths of de-Broglie waves for electrons in…

If $^{\prime} \lambda_{1}$ ' and ' $\lambda_{2}$ ' are the wavelengths of de-Broglie waves for electrons in first and second Bohr orbits in hydrogen atom, then $\left(\frac{\lambda_{1}}{\lambda_{2}}\right)$ is equal to (Energy in $1^{\text {st }}$ Bohr orbit $=-13.6 \mathrm{eV}$ )
  1. $\frac{1}{5}$
  2. $\frac{1}{2}$
  3. $\frac{1}{4}$
  4. $\frac{1}{3}$

Solution

The de-Broglie wavelength of an electron in the $n$-th orbit is inversely proportional to the radius of the orbit. Since the radius for the first orbit is $R$ and for the second orbit is $4 R$, the de-Broglie wavelength in the second orbit is 4 times that in the first orbit. Thus, the wavelength ratio is: $\frac{\lambda_1}{\lambda_2}=4$ The energy in the $n$-th Bohr orbit is given by: $E_n=-\frac{13.6 \mathrm{eV}}{n^2}$ .

Asked in: MHT CET 2020 (12 Oct Shift 2)

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