If a centimolal aqueous solution of $\mathrm{K}_{3}\left[\mathrm{~F}_{\mathrm{e}}(\mathrm{CN})_{6}\right]$…

If a centimolal aqueous solution of $\mathrm{K}_{3}\left[\mathrm{~F}_{\mathrm{e}}(\mathrm{CN})_{6}\right]$ has degree of dissociation $0 \cdot 78$, what is the value of vant Hoff factor?
  1. 3.34
  2. 1.2
  3. 2.5
  4. 4.0

Solution

$\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right] \longrightarrow 3 \mathrm{~K}^{+}+\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{-}$ $\therefore \mathrm{n}=4$ van't Hoff factor (i) $=1+\alpha(n-1)=1+0.78(4-1)=3.34$

Asked in: MHT CET 2020 (16 Oct Shift 1)

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