Identify the correct statement from following

Identify the correct statement from following
  1. Lanthanoids have greater tendency to form complexes than actinoids.
  2. Actinoid contraction is greater than lanthanoid contraction.
  3. Hydroxides of actinoids are less basic than Lathanoid hydroxides.
  4. Binding energy of $4 \mathrm{f}$ - orbitals is lower that $5 \mathrm{f}$ - orbitals.

Solution

To determine the correct answer, let's analyze the options: 1. "Lanthanoids have greater tendency to form complexes than actinoids." - This is false because actinoids have a greater tendency to form complexes due to their higher charge density and variable oxidation states compared to lanthanoids. 2. "Actinoid contraction is greater than lanthanoid contraction." - This is true because the 5 f orbitals in actinoids are less shielded than the $4 f$ orbitals in lanthanoids. This causes a stronger actinoid contraction compared to lanthanoid contraction. 3. "Hydroxides of actinoids are less basic than lanthanoid hydroxides." - This is false because lanthanoid hydroxides are less basic than actinoid hydroxides due to lanthanoids having lower ionic radii and less shielding effect. 4. "Binding energy of $4 f$ orbitals is lower than $5 f$ orbitals." - This is false because $5 f$ orbitals in actinoids are less tightly bound than $4 f$ orbitals in lanthanoids. So Option 2 is Correct

Asked in: MHT CET 2020 (12 Oct Shift 2)

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