Identify ( P ) and ( Q ) in the following reaction: 2 CH 3 Cl + Si   → 570   K Cu  …

Identify (P) and (Q) in the following reaction:
2CH3Cl+Si 570 KCu powderPH2OQStraight chain polymer
  1. P: CH33SiClQ: CH33SiOH
  2. P: CH32SiCl2Q: CH32Si(OH)2
  3. P: CH32SiCl2Q: CH32Si(OH)Cl
  4. P: CH32SiCl2Q: CH32SiO

Solution

When methyl chloride reacts with silicon in the presence of copper as a catalyst at a temperature 573 K various types of methyl substituted chlorosilane of formula MeSiCl3, Me2SiCl2, Me3SiCl with small amount of Me4Si are formed. Hydrolysis of dimethyl dichlorosilane, CH32SiCl2 followed by condensation polymerisation yields straight chain polymers.

2CH3Cl+Si 570 KCu powderCH32SiCl2-2HCl+2H2OCH32SiOH2

Asked in: AP EAMCET 2021 (19 Aug Shift 1)

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