Identify $A$ and $B$ in the following reaction $\mathrm{CH}_3-\mathrm{CH}_3 \stackrel{B}{\longleftarrow}…

Identify $A$ and $B$ in the following reaction $\mathrm{CH}_3-\mathrm{CH}_3 \stackrel{B}{\longleftarrow} \mathrm{CH}_3 \mathrm{COOH} \stackrel{A}{\longrightarrow} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}$ $\text { A } \quad \text { B }$
  1. $\mathrm{HI}+$ red $\mathrm{P} \quad \mathrm{LiAlH}_4$
  2. $\mathrm{Ni} / \Delta \quad \mathrm{LiAlH}_4$
  3. $\mathrm{LiAlH}_4 \quad \mathrm{HI}+$ red P
  4. $\mathrm{Pd}_{-\mathrm{BaSO}_4} \quad \mathrm{Zn}+\mathrm{HCl}$

Solution

Acetic acid on reduction with lithium aluminiumhydride $\left(\mathrm{LiAlH}_4\right)$ gives ethyl alcohol while on reduction with $\mathrm{HI}$ and red $\mathrm{P}$ gives ethane. $ \mathrm{CH}_3 \mathrm{COOH} \stackrel{\mathrm{LiAlH}_4}{\longrightarrow} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH} $ ethyl alcohol $ \mathrm{CH}_3 \mathrm{COOH} \stackrel{\text { Red P }+\mathrm{HI}}{\longrightarrow} \mathrm{CH}_3-\mathrm{CH}_3 $ Hence, reagent $A$ and $B$ are respectively $\mathrm{LiAlH}_4$ and $\mathrm{HI} /$ red P

Asked in: AP EAMCET 2008

Practice more Alcohols Phenols and Ethers questions on Aicharya