Identify correct statements : (A) Primary amines do not give diazonium salts when treated with…

Identify correct statements :
(A) Primary amines do not give diazonium salts when treated with $\mathrm{NaNO}_2$ in acidic condition.
(B) Aliphatic and aromatic primary amines on heating with $\mathrm{CHCl}_3$ and ethanolic KOH form carbylamines.
(C) Secondary and tertiary amines also give carbylamine test.
(D) Benzenesulfonyl chloride is known as Hinsberg's reagent.
(E) Tertiary amines reacts with benzenesulfonyl chloride very easily.
Choose the correct answer from the options given below :
  1. (A) and (B) only
  2. (D) and (E) only
  3. (B) and (D) only
  4. (B) and (C) only

Solution


(C) Only primary amine gives carbyl amine test
(D)
$\mathrm{Ph}-\mathrm{SO}_2 \mathrm{Cl}$ ________ Hinsberg reagent
Benzene sulphonyl chloride
(E) Tertiary amine do not react with $\mathrm{Ph}-\mathrm{SO}_2 \mathrm{Cl}$
So correct options are (B) and (D) only

Asked in: JEE Main 2025 (28 Jan Shift 2)

Practice more Amines questions on Aicharya