How many grams of concentrated nitric acid solution should be used to prepare $250 \mathrm{~mL}$ of $2.0…

How many grams of concentrated nitric acid solution should be used to prepare $250 \mathrm{~mL}$ of $2.0 \mathrm{M} \mathrm{HNO}_3$ ? The concentrated acid is $70 \% \mathrm{HNO}_3$.
  1. $45.0 \mathrm{~g}$ conc. $\mathrm{HNO}_3$
  2. $90.0 \mathrm{~g}$ conc. $\mathrm{HNO}_3$
  3. $70.0 \mathrm{~g}$ conc. $\mathrm{HNO}_3$
  4. $54.0 \mathrm{~g}$ conc. $\mathrm{HNO}_3$

Solution

Given, molarity of solution $=2$ Volume of solution $=250 \mathrm{~mL}=\frac{250}{1000}=\frac{1}{4} \mathrm{~L}$ Molar mass of $\mathrm{HNO}_3=1+14+3 \times 16=63 \mathrm{~g} \mathrm{~mol}^{-1}$ $\because$ Molarity $\begin{aligned} & =\frac{\text { weight of } \mathrm{HNO}_3}{\text { mass of } \left.\mathrm{HNO}_3 \times \text { volume of solution ( } L\right)} \\ & \therefore \text { Weight of } \mathrm{HNO}_3=\text { molarity } \times \text { mol. mass } \\ & \times \text { volume }(\mathrm{L}) \\ & =2 \times 63 \times \frac{1}{4} \mathrm{~g}=31.5 \mathrm{~g} \\ & \end{aligned}$ It is the weight of $100 \% \mathrm{HNO}_3$. But the given acid is $70 \% \mathrm{HNO}_3$. $\therefore \text { Its weight }=31.5 \times \frac{100}{70} \mathrm{~g}=45 \mathrm{~g}$

Asked in: NEET 2013 (All India)

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