How many chiral compounds are possible on monochlorination of $2-$methyl butane ?
How many chiral compounds are possible on monochlorination of $2-$methyl butane ?
-
$8$
-
$2$
-
$4$
-
$6$
Solution
$\mathrm{H}_3 \mathrm{C}-\mathrm{CH}_2-\mathrm{CH}\left(\mathrm{CH}_3\right)-\mathrm{CH}_3$ on monochlorination gives
$\mathrm{H}_2 \mathrm{C}(\mathrm{Cl})-\mathrm{CH}_2-\mathrm{CH}\left(\mathrm{CH}_3\right)-\mathrm{CH}_3$
(I)
Achiral
$\mathrm{H}_3 \mathrm{C}-\mathrm{CH}(\mathrm{Cl})-\mathrm{CH}\left(\mathrm{CH}_3\right)-\mathrm{CH}_3$
(II)
Chiral

(III)
Achiral
(IV)
chiral
Asked in: JEE Main 2012 (Offline)
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