H 2   S ( 5 moles) reacts completely with acidified aqueous potassium permanganate solution. In this…

H2 S (5 moles) reacts completely with acidified aqueous potassium permanganate solution. In this reaction, the number of moles of water produced is x, and the number of moles of electrons involved is y. The value of (x+y) is

Solution

KMnO4H+Mn2+

S-2 S0

The number of electrons involved per molecule is called n-factor.

n-factor of KMnO4=5

n-factor of S-2H2 S=2

Moles×n-factor = number of equivalents 

nKMnO4×5=(5×2)H2 S

nKMnO4=2

2KMnO4+3H2SO4+5H2 SK2SO4+2MnSO4+5 S+8H2O

Number of moles of water produced = 8 

Number of moles of electrons involved =10

  x=8,y=10(x+y)=18

Asked in: JEE Advanced 2023 (Paper 2)

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