$x$ grams of water is mixed in $69 \mathrm{~g}$ of ethanol. Mole fraction of ethanol in the resultant…

$x$ grams of water is mixed in $69 \mathrm{~g}$ of ethanol. Mole fraction of ethanol in the resultant solution is 0.6 . What is the value of $x$ in grams?
  1. $54$
  2. $36$
  3. $180$
  4. $18$

Solution

According to question, $ \begin{aligned} & w_A=x \mathrm{~g}, m_A=18, X_A=1-0.6=0.4 \\ & w_B=69 \mathrm{~g}, m_B=46, X_B=0.4 \end{aligned} $ We know that, $ X_A=\frac{n_A}{n_A+n_B} $ $ \begin{gathered} \text { or } \quad 0.4=\frac{w_A / m_A}{w_A / m_A+69 / 46} \Rightarrow 0.4=\frac{\frac{x}{18}}{\frac{x}{18}+\frac{3}{2}} \\ 0.4 \times\left(\frac{2 x+54}{36}\right)=\frac{x}{18} \end{gathered} $ or $\quad 2 x+54=5 x$ or $3 x=54, x=18 g$

Asked in: AP EAMCET 2004

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