Given that ionization potential and electron gain enthalpy of chlorine are 13 eV and 4 eV respectively. The…

Given that ionization potential and electron gain enthalpy of chlorine are 13eV and 4eV respectively. The electronegativity of chlorine on Mulliken scale, approximately equals to
  1. 8.5eV
  2. 6.0eV
  3. 3.0eV
  4. 1.5eV

Solution

On Mulliken scale, E.N. \(=\frac{\mathrm{I} \cdot \mathrm{E}+\mathrm{E} . \mathrm{A}}{2}=\frac{13+4}{2}=8.5 \mathrm{eV}\) Mulliken values are nearly 2.8 time larger than Pauling value So, on Pauling scale \(=\frac{8.5}{2.8}=3 \mathrm{eV}\) So, correct answer is 8.5 eV according to Mulliken scale.

Asked in: JEE-TOPICTESTS-CHEMISTRY

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