Given below are two statements: Statement (I) : for ${\underset{\bullet \bullet}{\bullet \bullet}}_{\bullet…

Given below are two statements:
Statement (I) : for ${\underset{\bullet \bullet}{\bullet \bullet}}_{\bullet \bullet}^{\bullet} \mathrm{F}_3$, all three possible structures may be drawn as follows.

Statement (II) : Structure III is most stable, as the orbitals having the lone pairs are axial, where the $\ell \mathrm{p}-\mathrm{bp}$ repulsion is minimum.
In the light of the above statements, choose the most appropriate answer from the options given below:
  1. Statement I is incorrect but statement II is correct.
  2. Statement I is correct but statement II is incorrect.
  3. Both Statement I and statement II are correct.
  4. Both Statement I and statement II are incorrect.

Solution

Statement 1 is correct.
Statement 2 is incorrect since in $\mathrm{sp}^3 \mathrm{~d}$ hybridization; lone pair cannot occupy axial position.

Asked in: JEE Main 2025 (04 Apr Shift 2)

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