Given below are two statements: Statement - I: Along the period, the chemical reactivity of the element…
Statement - I: Along the period, the chemical reactivity of the element gradually increases from group to group .
Statement - II: The nature of oxides formed by group element is basic while that of group elements is acidic.
In the the light above statements, choose the most appropriate from the questions given below:
- Both statement I and Statement II are true.
- Statement I is true but Statement II is False.
- Statement I is false but Statement II is true.
- Both Statement I and Statement II is false.
Solution
The atomic and ionic radii, as we know, generally decrease in a period from left to right. As a consequence, the ionisation enthalpies generally increase (with some exceptions) and electron gain enthalpies become more negative across a period. In other words, the ionisation enthalpy of the extreme left element for a period is the least and the electron gain enthalpy of the element on the extreme right is the highest negative (Note: noble gases having completely filled shells have rather positive electron gain enthalpy values). This results in high chemical reactivity at the two extremes and the lowest in the centre.
Group - 1 elements form basic nature oxides. Metallic oxides are basic in nature because they react with dilute acids to form salt and water, while group - elements form acidic oxides, An oxide that exhibits the property of acids is called acidic oxide. Since they are acidic, they react with a base to form a salt. Non-metals react with oxygen to form acidic compounds of oxides which are held together by covalent bonds. Therefore, statement - II is true.
Asked in: JEE Main 2024 (30 Jan Shift 2)
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