Freundlich adsorption isotherms for the physical adsorption of a gas at temperature $T_1, T_2$ and $T_3$ are…

Freundlich adsorption isotherms for the physical adsorption of a gas at temperature $T_1, T_2$ and $T_3$ are shown in the graph given below. The correct relationship between $T_1, T_2$ and $T_3$ is
  1. $T_1 < T_2 < T_3$
  2. $T_3 < T_1 < T_2$
  3. $T_3 < T_2 < T_1$
  4. $T_2 < T_1 < T_3$

Solution

Lower the temperature more the adsorption. So, as the temperature increases adsorption decreases. According to Freundlich adsorption isotherm. $ \frac{x}{m}=k \cdot p^{1 / n}(n>1) $ where, $x$ is the mass of gas adsorbed. $ \begin{aligned} & \text { or } \quad \log \frac{x}{m}=\log k+\frac{1}{n} \log p \\ & \therefore \quad T_3 < T_2 < T_1 \end{aligned} $

Asked in: AP EAMCET 2018 (23 Apr Shift 1)

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