Formation of a solution from two components can be considered as: (i) Pure solvent $\rightarrow$ separated…
- $\Delta \mathrm{H}_{\text {soln }}=\Delta \mathrm{H}_1+\Delta \mathrm{H}_2+\Delta \mathrm{H}_3$
- $\Delta \mathrm{H}_{\text {soln }}=\Delta \mathrm{H}_1+\Delta \mathrm{H}_2-\Delta \mathrm{H}_3$
- $\Delta \mathrm{H}_{\text {soln }}=\Delta \mathrm{H}_1-\Delta \mathrm{H}_2-\Delta \mathrm{H}_3$
- $\mathrm{AH}_{\text {soln }}=\mathrm{AH}_3-\mathrm{AH}_1-\mathrm{AH}_2$
Solution
$\Delta$ Hsolution $ > 0$ or $\Delta$ Hsolution $< 0$, then these solutions are called non-ideal solutions.
Related Theory
The enthalpy of solution depends on the strengths of intermolecular forces of the solute and solvent. If the solution is ideal, and $\Delta \mathrm{H}$ solution $=0$, then
$\begin{aligned}
& \Delta H_{\text {solution }}=\Delta H_1+\Delta H_2+\Delta H_3=0 \\
& \Delta H_1+\Delta H_2=-\Delta H_3
\end{aligned}$
Asked in: NEET 2003