For which electrolyte the molar conductivity at infinite dilution can not be obtained graphically?

For which electrolyte the molar conductivity at infinite dilution can not be obtained graphically?
  1. $\mathrm{HNO}_3$
  2. $\quad \mathrm{H}_2 \mathrm{SO}_4$
  3. $\mathrm{CH}_3 \mathrm{COOH}$
  4. KCl

Solution

The molar conductivity of weak electrolyte like $\mathrm{CH}_3 \mathrm{COOH}$ does not vary linearly with square root of concentration as shown in the figure. As a result, $\Lambda_0$ cannot be determined by extrapolation method graphically unlike strong electrolytes.

Asked in: MHT CET 2024 (09 May Shift 1)

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