For the reaction, $\mathrm{H}_{2(\mathrm{~g})}+\mathrm{Br}_{2(\mathrm{~g})} \longrightarrow 2…

For the reaction, $\mathrm{H}_{2(\mathrm{~g})}+\mathrm{Br}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{HBr}_{(\mathrm{g})}, \mathrm{r}=\mathrm{k}\left[\mathrm{H}_2\right]\left[\mathrm{Br}_2\right]^{\frac{1}{2}}$ What is the molecularity and order of reaction respectively?
  1. Monomolecular and $\frac{1}{2}$
  2. Monomolecular and 1
  3. Monomolecular and $\frac{3}{2}$
  4. Bimolecular and $\frac{3}{2}$

Solution

Molecularity $=$ No of reactants $=2$ Order of reaction $=1+\frac{1}{2}=\frac{3}{2}$ Order of a reaction is an experimentally derived quantity and cannot be predicted from balanced equation. We can determine order from an equation only in case of an elementary reaction.

Asked in: MHT CET 2024 (16 May Shift 2)

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