For the reaction, $2 \mathrm{H}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{H}_2…
- -28.66 kJ
- 143.3 kJ
- 286.6 kJ
- 573.2 kJ
Solution
Reversing the above reaction, $2 \mathrm{H}_2 \mathrm{O}_{(l)} \longrightarrow 2 \mathrm{H}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})} \Delta_{\mathrm{d}} \mathrm{H}^{\circ}=573.2 \mathrm{~kJ} \mathrm{~mol}^{-1}$ $\therefore \quad$ For decomposition of 1 mole of water, $\mathrm{H}_2 \mathrm{O}_{(l)} \longrightarrow \mathrm{H}_{2(\mathrm{~g})}+\frac{1}{2} \mathrm{O}_{2(\mathrm{~g})} ; \Delta_{\mathrm{d}} \mathrm{H}^{\mathrm{o}}=286.6 \mathrm{~kJ} \mathrm{~mol}^{-1}$
Asked in: MHT CET 2024 (09 May Shift 2)