For the reaction of one mole of zinc dust with one mole of sulphuric acid in a bomb calorimeter, $\Delta U$…

For the reaction of one mole of zinc dust with one mole of sulphuric acid in a bomb calorimeter, $\Delta U$ and $w$ correspond to
  1. $\Delta U < 0, w=0$
  2. $\Delta U < 0, w < 0$
  3. $\Delta U>0, w=0$
  4. $\Delta U>0, w>0$

Solution

Bomb calorimeter commonly used to find the heat of combustion of organic substances, consists of a sealed combustion chamber, called a bomb. The reaction in a bomb calorimeter proceeds at constant volume so, $w=0$ and $\Delta U=q$. Hence, $\Delta U < 0, w=0$. :

Asked in: NEET 2015 (Phase 1)

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