For the following reaction, the equilibrium constant K e at 298   K is 1.6 × 10 17 . F e 2 + a q +…

For the following reaction, the equilibrium constant Ke at 298 K is 1.6×1017.
Fe2+aq+S2-aq FeSs
When equal volumes of 0.06 M Fe2+aq and 0.2 M S2-aq solutions are mixed, the equilibrium concentration of Fe2+aq is found to be Y×10-17M. The value of Y is __________

Solution

Fe2++S2-Fe S(s) ..... Kc=1.6×1017
t=0 : 0.03 M 0.1 M
t=t; 0.03-H 0.1 H
Since Kc>>1,
n0.03
[S2-]=0.1-0.031=0.07 M
Kc=Fe2+S2-=11.6×1017
Fe2+=11.6×0.07×10-17
y=11.6×0.078.93

Asked in: JEE Advanced 2019 (Paper 1)

Practice more Ionic Equilibria questions on Aicharya