For the equilibrium, A g ⇌ B g ,   ∆ H   is   - 40   kJ / mol . If the ratio…

For the equilibrium, AgBg, H is -40 kJ/mol . If the ratio of the activation energies of the forward Ef and reverse Eb reactions is 23 then:
  1. Ef=30 kJ/mol, Eb=70 kJ/mol
  2. Ef=70 kJ/mol, Eb=30 kJ/mol 
  3. Ef=80 kJ/mol, Eb=120 kJ/mol
  4. Ef=60 kJ/mol,Eb=100 kJ/mol

Solution

 Activation energy is the minimum amount of energy that must be provided for compounds to result in a chemical reaction.

AgBg ; H=-40 kJ/mole

H=Eaf-Eab=-40 kJ

EafEab=23

 Eaf=23Eab

23 Eab-Eab=-Eab3=-40 kJ

Eab=+120 kJ

Eaf=23×120=80 kJ

Asked in: JEE Main 2015 (11 Apr Online)

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