For $\mathrm{H}_{3} \mathrm{PO}_{3}$ and $\mathrm{H}_{3} \mathrm{PO}_{4}$, the correct choice is

For $\mathrm{H}_{3} \mathrm{PO}_{3}$ and $\mathrm{H}_{3} \mathrm{PO}_{4}$, the correct choice is
  1. $\mathrm{H}_{3} \mathrm{PO}_{3}$ is dibasic and reducing
  2. $\mathrm{H}_{3} \mathrm{PO}_{4}$ is diabasic and non-reducing
  3. $\mathrm{H}_{3} \mathrm{PO}_{4}$ is tribasic and reducing
  4. $\mathrm{H}_{3} \mathrm{PO}_{3}$ is tribasic and reducing

Solution

The structure of $\mathrm{H}_{3} \mathrm{PO}_{3}$ is as given below.


There are only two-OH groups and hence it is dibasic. The oxidation number of $\mathrm{P}$ in this acid is $+3$, whereas $\mathrm{P}$ may have $+5$ oxidation state also. Therefore, $\mathrm{H}_{3} \mathrm{PO}_{3}$ can be oxidised which means $\mathrm{H}_{3} \mathrm{PO}_{3}$ is a reducing agent.

Asked in: JEE-TOPICTESTS-CHEMISTRY

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