For an elementary reaction, X ( g ) ⟶ Y ( g ) + Z ( g ) , the t 1 / 2 is 10 minutes. In what period…

For an elementary reaction, X(g)Y(g)+Z(g), the t1/2 is 10 minutes. In what period of time would the concentration of X be reduced to 10% of its original concentration?
  1. 20 minutes 
  2. 33.2 minutes 
  3. 15 minutes 
  4. 25.2 minutes 

Solution

X(g)Y(g)+Z(g)

Let the concentration at t=0 = x

The concentration after time t=t = a-x=10%x = 0.1x

K=0.693t12=0.69310=0.0693

According to the integrated rate law,

t=1Klnaa-x=10.0693ln10.1=10.0693ln10=2.3030.0693=33.2

Hence, the time is equal to the 33.2 minutes

Asked in: AP EAMCET 2021 (20 Aug Shift 2)

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