For a reversible reaction A ⇌ B , the ∆ H forward reaction = 20   kJ   mol – 1 .…

For a reversible reaction AB, the H forward reaction =20 kJ mol1. The activation energy of the uncatalyzed forward reaction is 300 kJ mol1. When the reaction is catalysed keeping the reactant concentration same, the rate of the catalysed forward reaction at 27C is found to be same as that of the uncatalyzed reaction at 327C. The activation energy of the catalysed backward reaction is _______ kJ mol1.

Solution

As per the question 

To determine the activation energy of the catalyzed backward reaction, we need to use the Arrhenius equation and the given information.

The Arrhenius equation is given by: 

k=Ae(-Ea/RT)

Ae-300×103600×R=Ae-Ea300×R

1032=Ea300

Ea=150×103J mol1

Ea=150 kJ mol1

Activation energy of catalysed backward reaction

Energy of activation for backward reactionEb=Ea-H

=150-20=130 kJ mol1

Asked in: JEE Main 2023 (15 Apr Shift 1)

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