For a reaction $\mathrm{A} \rightarrow$ product, rate constant is $2 \times 10^{-2} \mathrm{~s}^{-1}$. The…

For a reaction $\mathrm{A} \rightarrow$ product, rate constant is $2 \times 10^{-2} \mathrm{~s}^{-1}$. The initial concentration of $\mathrm{A}$ is $1.0 \mathrm{~mol} \mathrm{dm}^{-3}$. What is the value of $\log \frac{1}{[\mathrm{~A}]_{\mathrm{t}}}$ after 100 seconds?
  1. $0.423 \mathrm{~mol} \mathrm{dm}^{-3}$
  2. $0.135 \mathrm{~mol} \mathrm{dm}^{-3}$
  3. $0.270 \mathrm{~mol} \mathrm{dm}^{-3}$
  4. $0.868 \mathrm{~mol} \mathrm{dm}^{-3}$

Solution

$\begin{aligned} & \mathrm{k}=2 \times 10^{-2} \mathrm{~s}^{-1} \text { (first order reaction) } \\ & 2.303 \log \frac{[\mathrm{A}]_0}{[\mathrm{~A}]_{\mathrm{t}}}=\mathrm{kt} \\ & \left([\mathrm{A}]_0=1 \mathrm{M}\right) \log \frac{1}{[\mathrm{~A}]_{\mathrm{t}}}=\frac{\mathrm{k}}{2.303} \times \mathrm{t}=\frac{2 \times 10^{-2} \times 100}{2.303}=0.868\end{aligned}$

Asked in: MHT CET 2021 (22 Sep Shift 1)

Practice more Chemical Kinetics questions on Aicharya