For a reaction A s ⇌ B s + C g the set of all correct statements are a) K is independent of A . b) K is…

For a reaction AsBs+Cg the set of all correct statements are

a) K is independent of A.

b) K is dependent on partial pressure of C at a given temperature.

c) ΔH will be independent of temperature.

d) ΔH is independent of the catalyst addition.

  1. a,b,c,d
  2. a,b only
  3. a,b,d only
  4. a,b,c only

Solution

Given reaction is 

AsBs+Cg

Equilibrium constant for this reaction KC = C concentration of solid is considered as one during heterogenous equilibrium. So, as we can see K is independent of A.

Similarly KP = PC So, K is dependent on partial pressure of C.

Note: Although the value of equilibrium constant does not depend on concentration of reactants or products at a given temperature.

Enthalpy change depends on temperature, but it is independent of catalyst used.

So, statement a,b and d are correct.

.

Asked in: JEE-TOPICTESTS-CHEMISTRY

Practice more EQUILIBRIUM questions on Aicharya