For a given exothermic reaction K p and K ' p are the equilibrium constants at temperatures T 1 and T 2…

For a given exothermic reaction Kp and K'p are the equilibrium constants at temperatures T1 and T2 respectively (T2.>T1 ). Assuming that heat of reaction is constant in temperatures range between T1 and T2, it is readily observed that:
  1. Kp>K'p
  2. Kp<K'p
  3. Kp=K'p
  4. Kp=1K'p

Solution

logK2K1=Ho2.303R1T1-1T2
T2>T1 So Kp> K'p (exothermic reaction)
(Since T2>T1 )

Asked in: NEET 2014

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