Following are the four molecules "P", "Q", "R" and "S". Which one among the four molecules will react with…

Following are the four molecules "P", "Q", "R" and "S".
Which one among the four molecules will react with $\mathrm{H}-\mathrm{Br}_{(\mathrm{aq})}$ at the fastest rate?

  1. R
  2. P
  3. Q
  4. S

Solution

Addition of $\mathrm{H}-\mathrm{Br}_{(\mathrm{aq})}$ to alkene follows electrophilic addition mechanism. In the rate determining step a carbocation intermediate is formed. Among $\mathrm{P}, \mathrm{Q}$, R \& S compound Q will form most stable carbocation intermediate since it is resonance stabilized.

Asked in: JEE Main 2025 (24 Jan Shift 1)

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