$\mathrm{Cr}(\mathrm{CO})_x$, find the value of $x$ ?

$\mathrm{Cr}(\mathrm{CO})_x$, find the value of $x$ ?
  1. 4
  2. 6
  3. 2
  4. 1

Solution

Here, $\mathrm{Cr}$ has zero oxidation state, as has zero oxidation state in the compound. So, at zero oxidation state the electronic configuration of $\mathrm{Cr}$ is $[\mathrm{Ar}] 4 s^1, 3 d^5$ that means $\mathrm{Cr}$ has 6 valencies, as $\mathrm{Cr}$ in this state is stable due to half-filled orbitals. Now, for 6 valencies, $6 \mathrm{CO}$ is required. Therefore, $x=6$ The compound is $\mathrm{Cr}(\mathrm{CO})_6$. Hence, the correct option is (2).

Asked in: JEE-TOPICTESTS-CHEMISTRY

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