Find the total number of moles of donor atoms present in one mole trioxalatocobaltate(III) ion.

Find the total number of moles of donor atoms present in one mole trioxalatocobaltate(III) ion.
  1. 6
  2. 3
  3. 12
  4. 4

Solution

In $\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$, three oxalate ligands are attached to the cobalt ion. Since oxalate is a bidentate ligand, each $\left(\mathrm{C}_2 \mathrm{O}_4\right)^{2-}$ has two donor oxygen atoms. 1 mole of $\left(\mathrm{C}_2 \mathrm{O}_4\right)^{2-} \equiv 2$ moles of donor atoms. $\therefore 1$ mole of $\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-} \equiv 3 \times 2=6$ moles of donor atoms.

Asked in: MHT CET 2024 (02 May Shift 2)

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